Despite name, millipedes don't have 1,000 legs & do not bite/sting. Primary defense is to curl into coil. Many species also emit poisonous liquid secretions or hydrogen cyanide gas through microscopic pores called odoriferous glands. Can irritate.
A blood agent is a toxic chemical agent that affects the body by being absorbed into the blood. They are fast-acting, potentially lethal poisons that typically manifest at room temperature as volatile colorless gases with a faint odor. Blood agents are either cyanide- or arsenic-based.
Blood agents work through inhalation or ingestion. As chemical weapons, blood agents are typically disseminated as aerosols and take effect through inhalation. Due to their volatility, they are more toxic in confined areas than in open areas. Chemistry
Chemical warfare (CW) involves using the toxic properties of chemical substances as weapons. This type of warfare is distinct from nuclear warfare and biological warfare, which together make up NBC, the military acronym for nuclear, biological, and chemical (warfare or weapons), all of which are considered "weapons of mass destruction" (WMD). None of these fall under the term conventional weapons which are primarily effective due to their destructive potential. Chemical warfare does not depend upon explosive force to achieve an objective. Rather it depends upon the unique properties of the chemical agent weaponized. A lethal agent is designed to injure or incapacitate the enemy, or deny unhindered use of a particular area of terrain. Defoliants are used to quickly kill vegetation and deny its use for cover and concealment. It can also be used against agriculture and livestock to promote hunger and starvation. With proper protective equipment, training, and decontamination measures, the primary effects of chemical weapons can be overcome. Many nations possess vast stockpiles of weaponized agents in preparation for wartime use. The threat and the perceived threat have become strategic tools in planning both measures and counter–measures.